Transient inhomogeneous flow patterns in supercooled liquids under shear
نویسندگان
چکیده
منابع مشابه
Supercooled liquids under shear: theory and simulation.
We analyze the behavior of supercooled fluids under shear both theoretically and numerically. Theoretically, we generalize the mode-coupling theory of supercooled fluids to systems under stationary shear flow. Our starting point is the set of generalized fluctuating hydrodynamic equations with a convection term. A nonlinear integrodifferential equation for the intermediate scattering function i...
متن کاملSupercooled liquids under shear: A mode-coupling theory approach
We generalize the mode-coupling theory of supercooled fluids to systems under stationary shear flow. Our starting point is the generalized fluctuating hydrodynamic equations with a convection term. The method is applied to a two dimensional colloidal suspension. The shear rate dependence of the intermediate scattering function and shear viscosity is analyzed. The results show a drastic reductio...
متن کاملShear Viscosity and Diffusion in Supercooled Liquids
Under normal liquid conditions (at equilibrium or when moderately super cooled), molecular rotational and translational diffusion adhere closely to the sim ple Stokes-Einstein-Debye hydrodynamic model. Deeply supercooled "fragile" liquids present a striking exception, with translational diffusion alone occurring up to 102 — 103 times "too fast". This anomaly rests upon the statistics of fluct...
متن کاملThe origin of persistent shear stress in supercooled liquids.
The persistence of shear stress fluctuations in viscous liquids is a direct consequence of the non-zero shear stress of the local potential minima which couples stress relaxation to transitions between inherent structures. In simulations of 2D and 3D glass forming mixtures, we calculate the distribution of this inherent shear stress and demonstrate that the variance is independent of temperatur...
متن کاملInfluence of inherent structure shear stress of supercooled liquids on their shear moduli.
Configurations of supercooled liquids residing in their local potential minimum (i.e., in their inherent structure, IS) were found to support a non-zero shear stress. This IS stress was attributed to the constraint to the energy minimization imposed by boundary conditions, which keep size and shape of the simulation cell fixed. In this paper, we further investigate the influence of these bounda...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Soft Matter
سال: 2017
ISSN: 1744-683X,1744-6848
DOI: 10.1039/c7sm00178a